Grease three or four 8-inch cake pans and line the bottoms with parchment.
In a medium bowl, whisk together the flour, cocoa powders, sugar, baking soda, baking powder, salt, and espresso powder. Set aside.
Preheat your oven to 350°F.
In a large bowl, whisk together the oil, eggs, sour cream, buttermilk, and vanilla.
Add the dry ingredients to the wet ingredients, and as you whisk, slowly pour in the hot coffee. Mix until everything is just combined. The batter will be very thin.
Divide the batter evenly between the pans and bake for 15–20 minutes, or until a toothpick comes out with just a few moist crumbs.
Let the cakes cool completely on a rack before removing them from the pans.